1,3,5-Trichloro-2-methoxybenzene
نویسندگان
چکیده
The meth-oxy group of the title compound, C(7)H(5)Cl(3)O, is rotated out of the plane of the aromatic ring system, with a dihedral angle of 84.11 (13)°, due to the two bulky ortho-chloro substituents.
منابع مشابه
N 2,N 2,N 4,N 4,N 6,N 6-Hexapropyl-1,3,5-triazine-2,4,6-triamine
The title compound, C(21)H(42)N(6), was prepared by the reaction of 2,4,6-trichloro-1,3,5-triazine with dipropyl-amine. The structure of the mol-ecule is tripodal.
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Herein we report a parallel solid-phase synthesis of 1,3,5-triazine based nucleoside analogues by a three-step substitution, starting from 2,4,6-trichloro-1,3,5-triazine. A library of 80 galactosyl-1,3,5-triazine compounds was prepared in high purity without extensive reaction conditions or tedious purification, suggesting the generality of this method.
متن کامل6-Chloro-N 2,N 4-di-p-tolyl-1,3,5-triazine-2,4-diamine dimethylformamide monosolvate
The title compound, C(17)H(16)ClN(5)·C(3)H(7)NO, was prepared by reaction of p-toluidine with 2,4,6-trichloro-1,3,5-triazine at room temperature. The dihedral angles between the triazine ring and the pendant rings are 3.61 (12) and 53.11 (12)°. An intra-molecular C-H⋯N inter-action occurs. The packing is stabilized by N-H⋯N and N-H⋯O hydrogen bonds and C-H⋯π and π-π [centroid-centroid distance ...
متن کاملTrimethyl 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(azanediyl)]triacetate
The title compound, C(12)H(18)N(6)O(6), was synthesized via nucleophilic substitution by reacting 2,4,6-trichloro-1,3,5-triazine with glycine methyl ester hydro-chloride in reflux (dried toluene) under anhydrous atmosphere. Individual mol-ecules self-assemble via strong N-H⋯O hydrogen bonds into supra-molecular double tapes running parallel to the [010] crystallographic direction. The close pac...
متن کاملSynthesis and conformational analysis of constrained ethylene-bridged bis(hydroxylamino-1,3,5-triazine) compounds as tetradentate ligands; structure of rigid dinuclear Ti(IV) complex.
Ethylene-bridged bis(hydroxylamino-1,3,5-triazine) compounds, that may serve as tetradentate ligands, were synthesized in three steps from 2,4,6-trichloro-1,3,5-triazine. These compounds demonstrate different rotation restrictions around the C(Ar)-N bonds due to their distinctive electronic structure as apparent from their resonative contributors. A dinuclear complex Ti 2(mu-L)2(OiPr)4 (L = bis...
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